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组合 (zu3he2) can be used to describe the process of assembling or combining two or more things. For example, 我们将两种材料组合在一起 (wǒmen jiāng liǎng zhǒng cáiliào zǔhé zài yīqǐ) means "We combined two materials together". It can also be used to describe the result of the combination, such as 我们创造了一个新的组合 (wǒmen chuàngzàole yīgè xīn de zǔhé) which means "We created a new combination".
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结合 (jie2he2): to combine, to join together. This word is often used to describe the combination of two or more elements to form a whole.
联合 (lian2he2): to unite, to join together. This word is often used to describe the union of two or more entities to form a single entity.
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组合 is more appropriate to use when referring to the combination of two or more elements to form a new entity. For example, when referring to the combination of two or more people, objects, or ideas to form a new entity, 组合 is more appropriate than other words such as 合并 (hé bìng) which means "merge".
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